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Valero Energy
Annual Report 2006

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FY2006 Annual Report · Valero Energy
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Best	Earnings	in	Valero’s	History

Table of Contents

1	

		 Our	Financial	Highlights

3		 		 A	Letter	to	our	Shareholders

6		 		 A	Look	at	our	Company	from	Coast	to	Coast

9		 		 Making	Valero	a	Global	Force	in	Refining

11				 Developing	One	of	the	World’s	Most		

	 Complex	Refining	Systems

13				 Turning	Retail	and	Wholesale	into		

	 World-Class	Competitors

15				 Strong	Safety,	Reliability	&	Environmental		
Initiatives	Make	a	World	of	Difference

17				 Making	our	World	a	Better	Place

18				 Financial	Information

24				 Our	Board	of	Directors

25				 Shareholder	Information

	
	
	
	
Best	Earnings	in	Valero’s	History
O u r   F i n a n c i a l   H i g h l i g h t s

(Millions of Dollars, Except per Share Amounts)

operating revenues 

operating income 

net income 

earnings per common share – 
  assuming dilution 

total assets 

stockholders’ equity 

2006
$ 91,833 
$  8,010 
$  5,463 

8.64 
$ 
$ 37,753 
$ 18,605 

2005

$  82,162

$  5,459

$  3,590

$ 

6.10

$  32,798

$  15,050

capital expenditures and deferred 
  turnaround and catalyst costs 

$  3,756 

$  2,574

S u M M A R y 	 A n n u A L 	 R E P O R T
In an effort to provide shareholders with more effective communications,  
Valero Energy Corporation has adopted a summary annual report format, which  
provides condensed financial disclosure. The company’s full financial statements 
are contained in its Annual Report on Form 10-K for the year ended  
December 31, 2006, which is provided to all shareholders.

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3/19/07   5:08:11 PM

Letter to Shareholders
and CEO Portrait

Valero’s Executive Management Team  
Pictured left to right:  Joe Gorder, Executive Vice President – Marketing & Supply; Rich 
Marcogliese, Executive Vice President – Operations; Greg King, President; Bill Klesse, CEO & 
Chairman of the Board; Gene Edwards, Executive Vice President – Corporate Development & 
Strategic Planning; and Mike Ciskowski, Executive Vice President & Chief Financial Officer.

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3/19/07   5:08:25 PM

 
A Le tte r to our Shareholders

In today’s rapidly changing world, 
companies need every advantage to 
compete and succeed.  At Valero, 
we have worked hard to recruit 
employees, develop strategies 
and acquire assets that give us a 
competitive edge and make us a 
world-class competitor.

Valero has grown from a regional 
energy company with a single refinery 
to become North America’s largest 
refiner, with a system of 18 refineries 
stretching from California to the 
Caribbean and a combined throughput 
capacity of 3.3 million barrels per 
day.  Our geographic diversity and 
operating flexibility allow us to react 
quickly to shifts in the marketplace.  
We are also the leader in refinery 
conversion capacity, which allows us 
to upgrade low quality feedstocks into 
higher value clean products, giving us 
a competitive advantage.

A growing economy and strong 
demand for clean-burning fuels, 
combined with the size and 
complexity of our refining system 
and the best employees in the 
business, allowed us to capitalize on 

healthy margins and strong feedstock 
differentials to make 2006 the best 
year in Valero’s history.  In 2006, 
we achieved a record $8.5 billion 
of operating income and after-tax 
earnings of $5.5 billion, or $8.64 per 
share.

We have shared this success with you, 
our shareholders.  We increased our 
dividend twice in 2006, and in January 
2007 we increased it an additional 
50 percent, raising our quarterly cash 
dividend to $0.12 per share.  We also 
invested $2 billion to buy back  
35 million shares in 2006, and we  
will continue buying back our shares 
in 2007.

In addition, we finished 2006 with a 
very healthy balance sheet, having a 
cash balance of nearly $1.6 billion 
and a debt-to-capitalization ratio of 
just 16 percent.  We boosted our cash 
flow by contributing our financial 
interest in Valero L.P. to Valero GP 
Holdings, LLC and completed two 
public offerings to sell our ownership 
stake in that new company.  After-
tax proceeds from these transactions 
totaled $555 million, and the 

separation better positioned both 
companies for future growth.  

As we have demonstrated, we are 
taking a very balanced approach 
with our cash flow.  Besides returning 
cash to you, our shareholders, our 
capital expenditures in 2006 were 
$3.75 billion.  For 2007, our capital 
expenditures are expected to continue 
in the $3.5 billion range.  We will 
pay down high interest rate debt 
and continue looking into potential 
acquisitions.  But, any acquisitions 
must come at the right price and fit our 
acquisition criteria.  The credit market 
has recognized Valero’s financial 
strength, with two upgrades this year 
in our credit rating to BBB/stable 
outlook, which reduces our costs.  
Our goal is to improve our returns 
on investment and equity to provide 
industry-leading value to you over the 
long run. 

One of the ways we will improve 
returns is through the significant 
opportunities we have to generate 
earnings internally from improved 
performance.  We have acquired 
many refineries that did not receive 

5-Year Total Cumulative
Shareholder Return

$600

$500

$400

$300

$200

$100

$0

Valero Energy 
Corporation

Peer Group

S&P 500

12/01

12/02

12/03

12/04

12/05

12/06

Source: Valero’s Form 10-K for 2006.

Va l e r o   e n e r g y   C o r p o r a t i o n

3     

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returning More Cash than  
ever to Shareholders

50%

Valero earnings  
payout ratio

40%

(Dividends + 

Buybacks)/

earnings

30%

20%

10%

0%

2003   2004   2005   2006

Krotz Springs and Three Rivers 
refineries.  VPP Star Site status is the 
highest level of safety certification that 
OSHA offers, and today Valero has 
11 of the 23 U.S. refineries that have 
achieved Star Site status.  As we are 
continuing these VPP efforts, we are 

One of the ways 
we will improve 
returns is through 
the significant 
opportunities we 
have to generate 
earnings internally 
from improved 
performance.

increasing awareness and commitment 
to our process safety management 
program. 

We have also made great strides in 
reducing emissions at our refineries.  
Flue gas scrubbers are state-of-the-
art pollution prevention systems that 
reduce emissions of sulfur dioxide and 
particulate matter, thereby enhancing 
air quality.  In 2006, we added three 

new flue gas scrubbers, raising our 
total to 10 – more than any other 
refining company in North America.

What’s more, we are investing in 
the latest technology to improve 
energy efficiency at our refineries.  
In doing so, we can reduce fuel 
consumption and reduce carbon 
dioxide emissions by approximately 
2 million tons per year over the 
next several years.  Though we are 
uncertain about the science, we are 
concerned about climate change 
issues and will continue to work to 
reduce our carbon dioxide emissions 
from existing equipment.  It should 
be noted that when new regulations 
are implemented that change the 
specifications of fuels, like removing 
sulfur, it requires a refinery to increase 
heat and power consumption for the 
new process units, which increases 
carbon dioxide emissions.  Clearly, 
these are complex issues facing us all 
and a collaborative approach must be 
taken to find appropriate solutions.

Transportation fuels produced from 
crude oil are the most economic 
for the consumer.  Our industry is 
extremely efficient in refining crude 
oil into products that improve our 
customers’ lives.  Many programs 
being considered to substitute 
alternative fuels for crude oil derived 

adequate capital investment prior to 
our ownership.  As we increase their 
complexity, improve energy efficiency, 
enhance reliability and apply best 
practices throughout our system, 
we believe we can improve annual 
operating income by over $1 billion 
within the next five years.  We will 
also increase our capacity utilization 
by reducing both planned and 
unplanned downtime.  Realizing this 
improved performance goal will be a 
key to our future success.

Of course, personal safety continues 
to be our top priority for all of our 
operations.  As I always tell our 
employees, “I want you to go home 
from work every day the same way you 
came, just tired.”  In 2006, our refining 
network reached a record-best total 
recordable injury rate of 0.92, which 
is 25 percent better than the three-year 
industry average of 1.22 reported by 
the National Petrochemical & Refiners 
Association.  We achieved this record 
while integrating the former Premcor 
refineries, acquired in September 
2005, into our system.

 In 2006, we also had four refineries 
become certified or re-certified as 
Star Sites in the Occupational Safety 
and Health Administration’s Voluntary 
Protection Program (VPP).  These 
included our Benicia, St. Charles, 

4     

Va l e r o   e n e r g y   C o r p o r a t i o n

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refined products require subsidies to 
be competitive with crude oil based 
transportation fuels.  We believe that 
free markets should be allowed to 
determine the fuels we use and the 
prices we pay for them.  

Another ongoing initiative is the 
growth of the Valero brand.  Valero 
now has approximately 5,800 retail 
and branded wholesale sites following 
our expansion into the Great Lakes 
and Pacific Northwest regions last 
year.  We continue to brand outlets 
within our marketing area, and we 
announced an agreement with Susser 
Petroleum of Corpus Christi, Texas in 
August 2006 to put the Valero brand 
on over 300 of their locations in 
Texas and Oklahoma.  The deal made 
Valero the No. 1 wholesale rack fuel 
marketer in Texas, with 1,900 branded 
wholesale and company-owned 
locations and significant unbranded 
sales volumes around the state.

Our retail operations, which represent 
the company-operated stores, had 
their best year ever in earnings per 
store in 2006, and Valero was named 
Chain of the Year by Convenience 
Store Decisions magazine.  Even with 
these successes, we are continuing 
to implement aggressive profit 

improvement initiatives for our retail 
organization.

Of course, none of these successes 
would have been possible without 
the dedication and hard work of our 
employees, who were responsible for 
Valero once again being named to 
Fortune magazine’s list of the 100 Best 
Companies to Work For.  With this 
year’s ranking at No. 22, Valero has 
been in the top 25 for the last three 
consecutive years, and we have been 
named to the list in each of the past six 
years that we have been eligible. 

We have a very strong caring 
and sharing commitment to the 
communities in which we live and 
work.  With the company match, our 
employees raised a record $13 million 
for Valero’s United Way campaign 
and set a volunteer record with nearly 
275,000 hours donated to worthy 
causes.  Our employees also made 
it possible for the 2006 Valero Texas 
Open and Benefit for Children Golf 
Classic to raise a record $7 million 
for charity, the largest contribution 
in PGA TOUR history.  We thank our 
customers, contractors and suppliers 
for their generosity and support of this 
event.

2006 was a record year in every way 
for Valero because everyone from 
our board members and executives 
to our employees made countless 
contributions to our success.  I thank 
everyone for their support, hard work, 
dedication and commitment to safety 
and excellence.  We also thank our 
customers for their business and thank 
our suppliers and contractors who 
make tremendous efforts toward our 
goal of improved operations.

We also thank Bill Greehey who 
stepped down as Chairman of the 
Board of Directors in January 2007 
following his retirement as Chief 
Executive Officer at the end of 2005.  
All of us at Valero thank Bill for his 
leadership and commitment to our 
success over the years.

Thanks to the outstanding members 
of our team, we are ready for the 
future and are in a great position to 
execute our strategies.  I thank you, 
our shareholders, for your investment 
in our company and your confidence 
in us.  We are looking forward to 
making our operations even better and 
strengthening our position as a world-
class competitor in the years to come.

CEO & Chairman of the Board

Higher 
Highs

Higher 
Lows

$8

$7

$6

$5

$4

$3

$2

$1

$0

 1998-2002   1999-2003   2000-2004   2001-2005   2002-2006

 USGC 5-3-2 Product Margin 
(US Gulf Coast margin calculated with 
the ratio of 5 barrels of crude oil vs. 
three barrels of gasoline and two 
barrels of heating oil)

50/50 Arab Light/Medium
Sour Crude Oil Differentials 

Va l e r o   e n e r g y   C o r p o r a t i o n

5     

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A Lo o k at our Company 
f r o m   C o a s t   t o   C o a s t 

In 1980, Valero was a regional energy 
company with total assets just shy 
of $650 million, operations solely in 
Texas, and less than 1,600 employees 
on its payroll.

Today, Valero has assets of $38 
billion, including 18 refineries and 
approximately 5,800 retail and 
branded wholesale locations across 
North America.   

As the map on  
the opposite page 
clearly illustrates,  
it’s a sea of Valero  
teal and gold from
coast to coast.

In fact, Valero is the 15th largest 
company on the Fortune 500, with 
nearly $92 billion in annual revenues 
and almost 22,000 employees. It has 
been ranked No. 1 among the world’s 
refining and marketing companies for 
the past two years at the Platts Top 250 
Global Energy Company Awards.   

With a combined throughput capacity 
of approximately 3.3 million barrels 
per day (BPD), Valero is the largest 
refiner in North America and the most 
geographically diverse among all U.S. 
refiners.  With a sizeable presence 
in the four key U.S. refining regions, 
Valero is able to capitalize on the 
upswings in regional margins since 
they don’t always move together.  

Beyond its size, Valero also benefits 
from its ability to process more low-
quality, low-cost feedstocks than 
its peers.  Because it has one of the 
world’s most complex refining systems, 
the company has been able to turn 
great feedstock differentials into great 
earnings.

Valero has achieved these results by 
acquiring refineries for a fraction of 
their replacement value and then 
investing in them to make them 
significantly more profitable. Now the 
company is building on this success by 
focusing on reliability initiatives, better 
cost control and energy efficiency. 

On the marketing side, Valero 
is putting the same emphasis on 
improving profitability in its retail 
and wholesale operations.  Valero’s 
brand is going up at a breakneck 

pace at distributor sites across the 
country, taking product out of the spot 
market and selling it into the branded 
wholesale channel for a higher margin.  
At the same time, the retail division 
is implementing profit improvement 
initiatives that will reduce its costs and 
grow in-store sales.

Exploring opportunities to improve 
returns on capital and overall 
performance throughout its operations 
is making Valero a better investment 
for the long term.  

Just as importantly, the company 
continues to make safety a top priority 
and remains focused on environmental 
excellence.  Valero’s employees 
also remain committed to their 
communities – volunteering in record 
numbers and giving record donations 
to charity. 

For all of these reasons, Valero 
has been recognized as a world-
class competitor in operational 
excellence, refining complexity, 
retail and wholesale marketing, 
safety performance, environmental 
stewardship and community service.  
So it’s easy to see why Valero truly is a 
world-class company.

Valero’s throughput Capacity

From 170,000 BpD  
to 3.3 Million BpD

3MM

2MM

1MM

1996   1997  1998  1999  2000  2001  2002  2003  2004  2005  2006

Houston 

Krotz 
Springs

texas City

paulsboro

aruba

Benicia

St. Charles

Corpus

Christi

east & 

Huntway

ardmore

Denver*

McKee

Quebec City

three rivers

Wilmington

Delaware City

lima

Memphis

port arthur

*Denver refinery was divested in 2005.

6     

Va l e r o   e n e r g y   C o r p o r a t i o n

 
Krotz Springs

Ardmore

St. Charles

Memphis

Lima

Delaware City

Paulsboro

Quebec City

Aruba

CAnADA

SAn AnTOniO

ARUBA
Caribbean Sea

Benicia

Wilmington

McKee

San Antonio

Three Rivers

 Corpus Christi
(East & West)

Texas City

Houston

Port Arthur

d
n
e
g
e
L

Retail & Branded 
Wholesale Presence

Wholesale 
Marketing Presence

Valero Refineries

Cameron Highway  
Oil Pipeline Project

Third-Party 
Off Shore Platforms

Valero Headquarters

VLO AR pages 1-13   9

3/19/07   5:09:57 PM

Va l e r o   e n e r g y   C o r p o r a t i o n

7     

Valero got its start in refining with the Corpus Christi refinery (pictured), which remains one 
of the most technologically advanced plants in the world. Over the years, the company has 
assembled the best workforce, acquired great assets, upgraded and expanded those plants 
and developed best practices, providing lots of opportunities for the company  
to improve returns and remain competitive in the coming years.

Making	Valero	 	
A   G l o b a l   F o r c e   i n   R e f i n i n g

Realizing	that	the	time	was	right	to	
enter	the	refining	business,	Valero	
in	1997	began	buying	undervalued	
refineries	and	investing	to	expand	and	
improve	them.	A	decade	later,	Valero	
has	assembled	an	18-refinery	system	
that’s	the	largest	in	north	America	in	
terms	of	throughput	capacity.

Valero	bought	its	plants	at	a	fraction	
of	their	replacement	cost	as	other	
companies	were	abandoning	the	
refining	business	at	a	cyclical	low.	As	
the	years	went	by,	Valero’s	strategy	of	
acquiring	plants	at	value	prices	was	
proven	correct	as	margins	surged	and	
analysts	declared	a	“Golden	Age	of	
Refining.”	And	now,	with	its	size	and	
geographic	diversity,	Valero	is	a	vibrant	
competitor	on	an	international	scale.

By	investing	in	and	upgrading	its	
refineries	since	1980,	Valero	has	
added	573,000	barrels	per	day	(BPD)	
in	refining	capacity	–	an	amount	
nearly	twice	the	capacity	of	Valero’s	
Port	Arthur	refinery,	one	of	the	largest	
in	its	system.	

When	other	refiners	scrambled	to	
add	capacity	to	take	advantage	of	this	

“Golden	Age,”	Valero	was	uniquely	
positioned	to	carefully	choose	which	
projects	best	fit	its	strategy	and	
provided	the	highest	returns.	In	2006,	
as	construction	costs	skyrocketed	

The company 
has acquired the 
best employees 
and developed 
the best practices 
in the industry, 
providing significant 
opportunities to 
improve annual 
operating income.

across	the	global	refining	industry,	
Valero	was	able	to	implement	its	most	
ambitious	capital	budget	ever,	while	
still	keeping	costs	at	approximately	
$3.75	billion.

Another	advantage	of	Valero’s	strategy	
is	the	expertise	it	has	gained	along	with	
the	refineries.	By	applying	this		
expertise	in	conjunction	with	upgrades,	
expansions,	energy	efficiency	and	
reliability	enhancements,	Valero	is	
targeting	$1	billion	of	operating	income	
improvements	in	the	next	five	years.

Valero’s	strategy	continues	to	pay	off.	
Current	capital	improvement	projects	
are	expected	to	add	another	
$250	million	in	operating	income	
in	2007.	This	includes	the	recently	
completed	expansion	at	the	Port	
Arthur	refinery	and	mild	hydrocracker	
units	in	the	works	at	the	Houston	and	
St.	Charles	refineries.	In	addition,	
grassroots	ultra-low-sulfur	diesel	units	
are	planned	for	the	Benicia	and	Corpus	
Christi	refineries.

A	successful	strategy	plus	world-
class	size,	complexity,	strength	and	
geographic	diversity	–	combined	with	
Valero’s	dedicated	and	hard-working	
employees	–	give	Valero	the	best	
refining	system	in	the	business.	It’s	a	
system	that	is	positioned	for	long-term	
success.

A Leader in Upgrading Capacity

Cat Cracking

Hydrocracking

Coking

MBpD

1,800

1,600

1,400

1,200

1,000

800

600

400

200

0

VLO  XOM   COP   RDS   BP   CVX   MRO   SUN   TSO

Valero’s upgrading capacity, which is the highest in its peer group, provides  
superior operational flexibility. note: includes U.S., Canada & Caribbean 
Source: Oil & Gas Journal, Company Web Sites  

Va l e r o   e n e r g y   C o r p o r a t i o n

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3/19/07   5:10:11 PM

 
 
Flexibility and Diversity Key to Valero’s  
Feedstock Strategy

number of Heavy, Sour Crudes  
& resids Used by Valero 

Source of Valero’s 2006 
Feedstock Consumption

Europe 7%

Rest of World 3%

45

40

35

30

25

20

2002   2003   2004   2005   2006
the num ber of dif ferent  heavy, sour and resid
feedstocks t hat Valero processes has grown   
fr om 27  to 40 i n j ust f ive years.

South
America
11%

Africa
12%

Middle 
East
17%

North America
50%

Oil tankers, like this one shown at the Port Arthur refinery’s dock, deliver crude 
oil from around the world to the company’s plants. Because of the complexity and 
flexibility of its system, Valero is able to choose from a wide selection of feedstocks, 
giving it an earnings advantage over many of its peers.

VLO AR pages 1-13   12

3/19/07   5:10:27 PM

$25 Continued Wide Differentials

$20

$15

$10

$5

$0

 2002  2003  2004  2005  2006

Resid

Maya

Arab  
Light/Medium 

D eve l opin g	One	of	the	World’s
M o s t   C o m p l e x   R e f i n i n g   S y s t e m s 

Valero’s	refining	system	isn’t	just	
the	biggest	in	north	America,	it’s	
also	one	of	the	most	complex.		This	is	
a	result	of	Valero’s	strategy	–	which	
stretches	back	to	the	beginning	of	the	
company	–	to	plan	for	a	future	that	
would	belong	to	companies	with	the	
ability	to	process	lower-cost	heavy,	
sour	feedstocks	into	premium,	clean-
burning	fuels.	That	strategy	has	paid	
off	for	Valero	ever	since	1984,	when	
it	entered	the	refining	business	by	
commissioning	its	Corpus	Christi	
refinery.

To	keep	its	competitive	advantage	over	
other	refiners,	Valero	has	acquired	
facilities	and	upgraded	them	to	meet	
this	strategy.	For	example,	the	Port	
Arthur	refinery	–	part	of	the	Premcor	
acquisition	in	2005	–	became	Valero’s	
most	profitable	plant	in	2006,	and	
including	expansions	through	the	first	
quarter	of	2007,	it	has	added	325,000	
barrels	per	day	(BPD)	of	medium	
and	heavy	sour	feedstocks	to	Valero’s	
capacity.		

Today,	Valero	has	more	catalytic	
cracking	capacity	than	some	refining	
companies’	total	conversion	capacity.	
The	same	is	true	of	Valero’s	coking	
capacity.		Sour	crude	oil	and	residual	
fuels	make	up	approximately		
60	percent	of	Valero’s	raw	materials	

input,	which	provides	tremendous	
cost	advantages.	As	the	world	moves	
toward	cleaner	fuel	standards,	the	
demand	for	easy-to-process	light,	
sweet	crude	is	growing.	Meanwhile,	
the	long-term	trend	for	most	new	
oil	being	produced	to	meet	rising	
worldwide	demand	typically	has	
been	heavier	and	more	sour,	and	not	

Valero’s ability to 
process a wide 
variety of feedstocks 
allows it to quickly 
take advantage of 
price differentials 
in the marketplace 
and mitigate supply 
disruptions.

all	refiners	are	as	well-positioned	as	
Valero	to	process	those	grades	of	
crude	oil.	As	those	trends	continue,	
the	difference	in	price	between	heavy	
or	sour	crude	oil	and	more	costly	
light,	sweet	crude	oil	should	remain	
favorable.

As	a	result	of	the	company’s	focus	on	
increasing	feedstock	flexibility,	the	

number	of	different	heavy,	sour	and	
resid	feedstocks	that	Valero	processes	
has	grown	from	27	in	2002	to	40	in	
2006.	Because	Valero	is	able	to	choose	
from	a	wide	selection	of	feedstocks,	
the	company	can	ensure	that	it’s	
getting	the	best	prices	the	marketplace	
is	offering.

And	with	Valero’s	large	throughput	
capacity,	changes	in	price	differentials	
rapidly	add	up.	Every	$1	difference	
between	sweet	and	sour	crude	oils	
impacts	Valero	by	about	$500	million	
per	year	in	operating	income.

Internal	projects	to	add	conversion	
capacity	have	given	Valero	even	more	
of	a	competitive	advantage.	A	new	
hydrocracker	reactor	at	the	Ardmore	
refinery	in	2006	should	contribute	
an	additional	$10	million	to	$12	
million	to	the	refinery’s	2007	operating	
income,	and	in	2007	new	mild	
hydrocracking	units	at	the	Houston	
and	St.	Charles	refineries	should	boost	
the	company’s	conversion	capacity	
even	higher.	

Valero’s	strategy	was	forward-
thinking	when	it	was	adopted	in	the	
early	1980s.		Today,	because	of	its	
tremendous	complexity	and	flexibility,	
the	company’s	refining	system	is	
considered	to	be	one	of	the	very	best	
in	the	world.	

VLO AR pages 1-13   13

3/19/07   5:10:42 PM

Va l e r o   e n e r g y   C o r p o r a t i o n

11     

Valero: Fastest Growing Brand in U.S.

U.S. Gasoline Sales Change by Brand, 2006 vs 2005

Valero

Industry Average

-7%    -5%    -3%    -1%    0%    1%    3%    5%    7%    9%    11%    13%     15%

Source: Lundberg Letter

For being a superior retailer and innovator, Valero’s retail network was named the 
2006 Chain of the Year by Convenience Store Decisions magazine. And, as a result 
of the branded wholesale network’s dramatic growth, Valero was named America’s 
“fastest-growing” gasoline marketer by Lundberg.

VLO AR pages 14-28.indd   14

3/19/07   5:14:48 PM

Turn i ng R etail and Wholesale
i n t o   Wo r l d - C l a s s   C o m p e t i t o r s 

For many years, the “Three F’s” 
– Fast, Friendly, and Fanatically Clean 
– have been the mantra of Valero’s 
retail operations.  In 2006, the Retail 
Division put added emphasis on 
another “F” – Fiercely Competitive.

Optimization, Upgrades and 
Profitability for Retail Sites

Valero’s retail organization continued 
to focus on converting its Corner Store 
network to the Valero fuel brand, 
upgrading its stores, offering quality 
products and strong in-store programs, 
and realizing cost efficiencies – all 
with the goal of making the network 
more competitive.  

This plan continues to reap rewards.  
Because the fuel brand and Corner 
Store offerings have been well-
received by customers, the Retail 
Division achieved its highest per-store 
earnings in history, growing per-store 
inside sales by 7 percent and gross 
profit by approximately 10 percent.  
Even though there were 41 fewer 
stores in its network in 2006 due to 
the divestiture of underperforming 
sites, the U.S. Retail Division still 
had a nearly 40 percent increase in 
operating income over 2005 and had 
its third-best earnings ever. 

In recognition of Valero’s dramatic 
growth and success in the retail 
industry in a very short period (the 

company had no branded retail 
operations in early 2000), Valero’s 
Corner Store network was named the 
2006 Convenience Store Chain of the 
Year by Convenience Store Decisions 
magazine.  This award annually 
honors a petroleum convenience store 
chain that has established itself as a 
superior retailer and innovator in its 
markets of operation.

“Valero is a model of consistency with 
an outstanding retail offering and the 
refining capacity to deliver consumers 
a good value on fuel with no dropoff 
in quality,” said the magazine’s Editor-
in-Chief John Lofstock. “Valero has 
managed to create some excitement 
in the market with new stores, strong 
in-store programs and a popular credit 
card network. With its commitment to 
retail excellence, Valero was an easy 
choice for Chain of the Year.”

Record Growth for Branded 
Wholesale Business

With the continued, aggressive growth 
of its branded wholesale locations 
as well as its unbranded wholesale 
volumes, Valero also was labeled 
America’s “fastest growing” gasoline 
marketer by the Lundberg Group, a 
well-respected source for information 
on the U.S. automotive fuel market.

Valero earned this distinction for 
its track record of growth in 2006, 

according to a study released in 
January 2007 by Lundberg. According 
to the study, Valero achieved nearly 15 
percent growth in gasoline sales over 
2005, while the rest of the industry 
had an average decline of about 1 
percent.

Thanks to Valero’s ability to provide 
reliable supply, competitive pricing, 
and a wide range of brand support 
programs, distributors have been 
signing on with the company in 
record numbers.  In fact, Valero 
contracted over 1,100 additional 
sites in 2006 alone, representing an 
additional 1.4 billion gallons in fuel 
sales per year.  Today, the branded 
wholesale network consists of nearly 
3,900 branded wholesale sites in the 
U.S., and the company’s goal is to 
have 7,000 U.S. sites by 2011.

Retail and Wholesale Strive to be 
Fiercely Competitive

Despite the success that the retail and 
wholesale organizations achieved in 
2006, they are continually working 
to make their operations even more 
successful.  In fact, they are currently 
implementing aggressive plans to 
further improve their profitability 
and achieve their ultimate goal of 
becoming Fiercely Competitive.  

Va l e r o   e n e r g y   C o r p o r a t i o n

13     

5

4.5

4

3.5

3

2.5

2

1.5

1

0.5

0

Refining Employee 
Injury Rates

Valero
UDS

Premcor
Basis

1996  1997  1998  1999  2000  2001  2002  2003  2004  2005  2006

UDS, Premcor & Basis are companies acquired by Valero.

Valero has invested nearly $700 million to construct state-of-the-art scrubber 
units like this one shown at the Delaware City refinery, one of two scrubber units 
that went on line at the refinery in 2006. Valero has scrubber units, which reduce 
sulfur dioxide emissions by over 93 percent, at 10 of its refineries.

VLO AR pages 14-28.indd   16

3/19/07   5:15:14 PM

St ron g Safety, Reliability
&   E n v i r o n m e n t a l   I n i t i a t i v e s   M a k e   a   Wo r l d   o f   D i f f e r e n c e   

In its annual listing of the “100 Best 
Companies to Work For,” Fortune 
magazine singled out Valero’s safety 
efforts as one of the main reasons 
the company once again ranked in 
the top 25 among the nation’s best 
employers.  This was not surprising 
because company officials have 
always believed that safety is the most 
fundamental way of caring for its 
employees, contract workers, and the 
communities where it operates.  

In 2006, Valero’s international refining 
network achieved a record-best 
total recordable injury rate (TRIR) 
of 0.92, which is 25 percent better 
than the three-year industry average 
of 1.22 reported by the National 
Petrochemical & Refiners Association.  
This record is the result of significant 
safety improvements at all of the 
refineries that Valero has acquired 
in recent years.  In fact, five Valero 
refineries finished the year without an 
employee lost-time injury.

Valero also works closely with its 
contract workforce to ensure that they 

maintain high safety standards, and 
as a result, the company reached a 
record contractor TRIR of 1.03 in 2006 
– a 26 percent improvement over the 
previous year. 

Since 2001, Valero employees and 
contractors have assumed even higher 
safety standards through participation 
in the OSHA Voluntary Protection 
Program (VPP), and today Valero has 
11 VPP Star Site refineries – more 
than any other refiner.  Out of 149 
U.S. refineries, only 23 have met the 
rigorous qualifications to earn this 
distinction, and Valero owns nearly 
half of those sites.  And, the company’s 
remaining refineries are on track to 
earn this prestigious certification in the 
coming years.

Another important benefit of VPP is the 
program’s strict adherence to OSHA’s 
rigorous Process Safety Management 
(PSM) regulations. Valero’s focus on 
PSM and its PSM-related programs 
are critical to the company’s efforts 
to maintain operational integrity and 
reliability at all of its sites.

Safe and reliable operations are also 
essential to strong environmental 
performance, another area where 
Valero has seen steady improvement 
in recent years. Between 2001 
and 2005, Valero reduced criteria 
emissions by 19,130 tons per year, or 
nearly 26 percent, while increasing 
charge capacity by almost 240,000 
barrels per year, or almost 14 percent.  

Much of Valero’s emission reductions 
are a result of major investments in 
state-of-the-art emission reduction 
technology.  And, these investments 
are in addition to the billions of dollars 
that Valero has invested to produce the 
clean fuels that adhere to new clean 
fuels standards and meet the growing 
demand of U.S. consumers.     

Valero will continue to be on the 
forefront of safety initiatives and 
environmental technology, and remain 
committed to sharing best practices 
from within its operations and 
throughout the industry.  After all, safe 
operations are a safe investment.

Valero’s Commitment to 
GHG Emission Reductions
As Valero continues working to meet 
our nation’s growing demand for clean 
fuels, the company is also committed 
to reducing greenhouse gas (GHG) 
emissions.  Valero is investing in the 
latest technology to improve combustion 
and energy efficiency at its refineries, 

which will reduce fuel consumption and 
carbon dioxide emissions over the next 
several years. 

in professional and public policy 
forums that address climate change 
and its potential impacts.  

Valero also supports market-based 
mechanisms and incentives to ensure the 
most economic sources of GHG emission 
reductions are realized.

Valero will continue to closely follow 
regulatory developments, and participate 

Through careful scientific, economic, 
and technical analysis, the company 
will work with all stakeholders to 
develop long-term measures that 
protect the environment.

VLO AR pages 14-28.indd   17

3/19/07   5:15:28 PM

Va l e r o   e n e r g y   C o r p o r a t i o n

15     

Valero Texas Open 
Charitable  
Contributions 

$7,000,000

$6,000,000

$5,000,000

$4,000,000

$3,000,000

$2,000,000

$1,000,000

$ 0

2001   2002*  2003   2004   2005   2006

* First year as the Valero Texas Open sponsor. 

Valero employee Kayla Moore and her son, Isaac, benefited greatly from the services of Seton Home, 
a San Antonio charity that receives United Way contributions and Valero Texas Open proceeds. 
Today, Kayla is giving back to her community by contributing her time and money to worthy causes.

VLO AR pages 14-28.indd   18

3/19/07   5:15:49 PM

Ma k in g o u r World a Better Place 
Va l e r o   E m p l o y e e s   G i v e   B a c k   t o   t h e i r   C o m m u n i t i e s

Charity has come full circle for Valero 
employee Kayla Moore. 

company’s philosophy of helping those 
in need.  

Once a vulnerable 17-year-old in 
foster care, Kayla learned about the 
importance of giving back when she 
benefited from the contributions that 
Valero made to a local charity that 
helped her out when she needed it 
most.

With the support of Seton Home – a 
beneficiary of Valero’s United Way 
contributions and Valero Texas Open 
proceeds – Kayla was able to provide 
a nice life for herself and her little boy, 
Isaac. Seton Home provided them with 
shelter and meals, taught Kayla how 
to care for her son, and enabled her 
to resume her education. Best of all, 
this agency helped her get a job at a 
company she loves – Valero! 

Kayla says that without Seton Home 
and Valero, she has no idea where 
she and Isaac would have ended up. 
Today, she is one of the people that 
makes Valero such a success.  And, 
this story of giving back has come full 
circle because Kayla has embraced the 

For 27 years, Valero employees like 
Kayla have been making a difference in 
the company’s communities. In 2006 
alone, Valero employees volunteered 
nearly 275,000 hours – doing 
everything from mentoring children 
and building Habitat for Humanity 
homes to delivering hot meals to 
homebound seniors. The company and 
its employees also contributed nearly 
$47 million to charities stretching from 
Canada to the Caribbean in 2006. 

There are countless examples of Valero 
employees’ generosity. They gave a 
record $13 million to United Way with 
company match, and helped raise an 
unprecedented $1.5 million for the 
MS Society through the Valero MS150. 
And, the company’s retail employees 
generated $1.1 million for Children’s 
Miracle Network and $1.3 million for 
the Muscular Dystrophy Association.

Before the company signed on as title 
sponsor, the most that the tournament 
had ever raised for charity was 
$500,000. In 2006, the tournament 
netted a record $7 million for charity, 
which was the largest contribution in 
the PGA TOUR’s history. So in the span 
of just five years, Valero helped take 
the tournament from the bottom of the 
TOUR’s charity rankings to the very top.   

What’s more, the Texas Open has 
brought in $25.6 million for charity 
over its entire 84-year history, and $21 
million of that amount has been raised 
since Valero became title sponsor just 
five years ago. 

Through their good works in the 
community, Valero employees have 
provided shelter for the homeless, 
meals for the hungry, healthcare for 
the disabled, companionship for the 
elderly, and much more. They have 
offered hope, healed hearts, and saved 
lives. 

But there’s no better example of 
Valero’s commitment to community 
service than the Valero Texas Open. 

Through their many contributions, they 
have made the world a much better 
place.

VLO AR pages 14-28.indd   19

3/19/07   5:16:21 PM

Va l e r o   e n e r g y   C o r p o r a t i o n

17     

Fin an cial Information
C o n d e n s e d   &   C o n s o l i d a t e d

The financial information presented 
on pages 19-23 of this summary 
annual report should be read in 
conjunction with Valero Energy 
Corporation’s complete Consolidated 
Financial Statements (including the 
notes) and Management’s Discussion 
and Analysis of Financial Condition 
and Results of Operations. This and 

other information about the company 
is contained in Valero’s Proxy 
Statement for the 2007 Annual 
Meeting of Stockholders and Valero’s 
Form 10-K for the year ended 
December 31, 2006. These 
documents are provided to all 
shareholders of record as of March 1, 
2007. In addition, anyone may 

request, without charge, a Form 10-K 
by writing or calling Valero’s Investor 
Relations Department. Address and 
contact information can be found on 
the inside back cover of this report. 
Valero’s 2006 Annual Report on Form 
10-K and the Proxy Statement also 
may be accessed via the company’s 
Web site at: www.valero.com.

R e p o r t   o f   I n d e p e n d e n t   R e g i s t e r e d   P u b l i c   A c c o u n t i n g   F i r m

To   t h e   B o a r d   o f   D i r e c t o r s   a n d   S t o c k h o l d e r s   
o f   Va l e r o   E n e r g y   C o r p o r a t i o n   a n d   S u b s i d i a r i e s :

We have audited, in accordance with 
the standards of the Public Company 
Accounting Oversight Board (United 
States), the consolidated balance 
sheets of Valero Energy Corporation 
and subsidiaries (the Company) as of 
December 31, 2006 and 2005, and 
the related consolidated statements of 
income, stockholders’ equity, cash 
flows and comprehensive income for 
each of the years in the three-year 
period ended December 31, 2006 
appearing in the Company’s 2006 
Annual Report on Form 10-K (not 

presented herein). In our report dated 
February 23, 2007, also appearing in 
that Annual Report, we expressed an 
unqualified opinion on those 
consolidated financial statements. Our 
report on the consolidated financial 
statements refers to changes in the 
method of accounting for purchases 
and sales of inventory with the same 
counterparty and stock compensation 
in 2006.  

In our opinion, the information set 
forth in the accompanying condensed 
consolidated balance sheets as of 

December 31, 2006 and 2005, and 
the related condensed consolidated 
statements of income and cash flows 
for each of the years in the three-year 
period ended December 31, 2006, is 
fairly stated, in all material respects, in 
relation to the consolidated financial 
statements from which it has been 
derived.

KPMG LLP
San Antonio, Texas
February 23, 2007

18     

Va l e r o   e n e r g y   C o r p o r a t i o n

RGB

condensed consolidated balance sheets

December 31, 

ASSeTS

Current Assets 

                           (millions of dollars)

2006 

2005 

$  10,760 

$ 

8,346 

Property, Plant and Equipment, Net 

  21,098 

  17,856 

Goodwill 

Intangible Assets, Deferred Charges  
    and Other Assets, Net 

4,211 

1,684 

4,926 

1,670 

ToTAl ASSeTS 

$  37,753 

$  32,798 

liAbiliTieS AND STockholDerS’  equiTy

Current Liabilities 

$ 

8,822 

$ 

7,375 

Long-Term Debt and Capital Lease Obligations,
   Less Current Portions 

Deferred Income Taxes 

Other Long-Term Liabilities 

4,657 

4,047 

1,622 

5,156 

3,615 

1,602 

Stockholders’ Equity 

  18,605 

  15,050 

ToTAl liAbiliTieS AND  
STockholDerS’ equiTy 

$  37,753 

$  32,798 

VLO AR pages 14-28.indd   21

3/19/07   5:16:51 PM

Va l e r o   e n e r g y   C o r p o r a t i o n

19     

    
 
 
 
 
 
 
 
 
 
 
 
 
condensed consolidated statements of income

yeAr eNDeD December 31, 

  2006 

  2005 

      2004

               (millions of dollars, except per share amounts)

operATiNg reveNueS 

coSTS AND expeNSeS:

Cost of Sales  
 Refining Operating Expenses 
Retail Selling Expenses 
 General and Administrative Expenses 
Depreciation and Amortization Expense 

ToTAl coSTS AND expeNSeS 

operATiNg iNcome 

equiTy iN eArNiNgS oF vAlero l.p. 

oTher iNcome (expeNSe), NeT 

 iNTereST AND DebT expeNSe, NeT 

miNoriTy iNTereST iN NeT iNcome oF  
   vAlero gp holDiNgS, llc 

iNcome beFore iNcome TAx expeNSe 

iNcome TAx expeNSe 

NeT iNcome  

preFerreD STock DiviDeNDS 

NeT iNcome ApplicAble To 
   commoN STock 

eArNiNgS per commoN ShAre 

   Weighted Average Common Shares Outstanding 
     (in millions) 

eArNiNgS per commoN ShAre —  
   ASSumiNg DiluTioN 

   Weighted Average Common Equivalent Shares  
     Outstanding (in millions) 

$  91,833  

$  82,162  

$  54,619 

  77,482  
3,785  
803  
598  
1,155  

  83,823  

8,010  

45  

351  

( 210 ) 

( 7 ) 

8,189  

2,726  

5,463  

2  

  71,673  
2,874  
758  
558  
840  

  76,703  

5,459  

41  

53  

( 266 ) 

—  

5,287  

1,697  

3,590  

13  

  47,797  
2,100  
696  
442  
605 

  51,640 

2,979 

39 

( 48 )

( 260 )

— 

2,710 

906 

1,804 

13 

$ 

$ 

5,461  

8.94  

$ 

$ 

3,577  

6.51  

$ 

$ 

1,791 

3.51 

611  

549  

510 

$ 

8.64  

$ 

6.10  

$ 

3.27 

632  

588  

552 

DiviDeNDS per commoN ShAre 

$ 

0.30  

$ 

0.19  

$ 

0.145 

20     

Va l e r o   e n e r g y   C o r p o r a t i o n

VLO AR pages 14-28.indd   22

3/19/07   5:17:03 PM

 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
condensed consolidated statements of cash flows

year ended december 31, 

     2006 

2005 

  2004

																																								(millions	of	dollars)

cash Flows From operating activities:
Net Income 
Adjustments to Reconcile Net Income
to Net Cash Provided by Operating Activities:
   Depreciation and Amortization Expense 
   Deferred Income Tax Expense 
   Changes in Current Assets, 
      Current Liabilities and Other, Net 

   Net Cash Provided by Operating Activities 

cash Flows From investing activities:
Capital Expenditures and Deferred Turnaround 
   and Catalyst Costs 
Proceeds from Sale of Valero GP Holdings, LLC 
Proceeds from Sales of Assets 
Major Acquisitions 
 Contingent Payments in Connection with Acquisitions 
Buyout of Assets Under Structured Lease Arrangements 

Other, Net 

   Net Cash Used in Investing Activities 

cash Flows From Financing activities:
Debt Borrowings (Repayments), Net 
Termination of Interest Rate Swaps 
Proceeds from Common Stock Offerings, Net 
Benefit from Tax Deduction in Excess 
   of Recognized Stock-based Compensation Cost 
Common and Preferred Stock Dividends 
Issuance (Repurchase) of Common Stock, Net 
Other 

   Net Cash Provided by (Used in) Financing Activities 

eFFect oF Foreign eXchange rate changes
   on cash 

net increase (decrease) in cash and
   temporary cash investments 

cash and temporary cash investments
   at beginning oF year 

cash and temporary cash investments
   at end oF year 

$ 

5,463  

$ 

3,590  

$  1,804 

1,155  
290  

(596 ) 

6,312  

(3,756 ) 
880  
64  
––  
(101 ) 
––  

(58 ) 

(2,971 ) 

(249 ) 
(54 ) 
––  

206  
(184 ) 
(1,898 ) 
(9 ) 

(2,188 ) 

1  

1,154  

436  

840  
255  

1,165  

5,850  

(2,574 ) 
––  
153  
(2,343 ) 
( 85 ) 
––  

(51 ) 

605  
345  

226 

  2,980 

  (1,596 )
–– 
108 
( 541 )
( 53 )
( 567 )

(36 )

(4,900 ) 

  (2,685 )

(874 ) 
—  
––  

—  
(106 ) 
(389 ) 
(13 ) 

(1,382 ) 

4  

(428 ) 

864  

71 
— 
406 

—  
( 79 ) 
( 205 ) 
(8 )

185

15 

495

369 

$ 

1,590  

$ 

436  

$ 

864 

Va l e r o   e n e r g y   C o r p o r a t i o n

21     

	
	
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
condensed consolidated 5-yr financial & statistical review

operATiNg reSulTS For yeAr  
eNDeD December 31:

Operating Revenues 

Operating Income 

Net Income 

(millions of dollars, except per share and per barrel amounts)

2006 

2005(a) 

2004(b) 

2003(c) 

2002

$ 91,833 

$ 82,162 

$  54,619 

$  37,969 

$ 29,048

$  8,010 

$  5,459 

$  2,979 

$  1,222  

$  5,463 

$  3,590 

$  1,804 

622  

$ 

$ 

471  

92

$ 

$ 

Earnings per Common Share  

$ 

8.94 

$ 

6.51 

$ 

3.51 

1.34 

$  0.22

Earnings per Common Share—  
  Assuming Dilution  

FiNANciAl poSiTioN AS oF December 31:

$ 

8.64 

$ 

6.10 

$ 

3.27 

$ 

1.27 

$  0.21

Current Assets  

$ 10,760 

$  8,346 

$  5,264 

$  3,817 

$  3,536 

Property, Plant and Equipment, Net  

  21,098 

  17,856 

  10,317 

8,195 

  7,412

Goodwill  

4,211 

4,926 

2,401 

2,402 

  2,580

Intangible Assets, Deferred Charges 

and Other Assets, Net  

Total Assets  

Current Liabilities 

Long-Term Debt and Capital Lease Obligations, 

Less Current Portions 

Deferred Income Taxes  

Other Long-Term Liabilities 

Company-Obligated Preferred  

Securities of Subsidiary Trusts 

Minority Interest in Valero L.P. 

1,684 

1,670 

1,410 

1,250 

937 

$ 37,753 

$ 32,798 

$  19,392 

$  15,664 

$ 14,465 

$  8,822 

$  7,375 

$  4,534 

$  3,064 

$  3,006  

4,657 

4,047 

1,622 

–– 

–– 

5,156 

3,615 

1,602 

— 

— 

3,901 

2,011 

1,148 

— 

— 

4,245 

  4,494 

1,605 

  1,241 

1,015 

927 

— 

— 

373 

116

Stockholders’ Equity 

  18,605 

  15,050 

7,798 

5,735 

  4,308

Total Liabilities and Stockholders’ Equity 

$ 37,753 

$ 32,798 

$  19,392 

$  15,664 

$ 14,465

22     

Va l e r o   e n e r g y   C o r p o r a t i o n

VLO AR pages 14-28.indd   24

3/19/07   5:17:17 PM

 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
c o m m u n i t y 
P h o t o

yeAr eNDeD December 31,

2006 

2005(a) 

2004(b) 

2003(c) 

  2002  

commoN STock DATA:

Dividends per Common Share 

$ 

0.30 

$ 

0.19 

$  0.145 

$  0.105 

$  0.10

Number of Shares Outstanding, 
  End of Year (in millions)  

Number of Registered Shareholders,  

  End of Year  

Market Price: 
  High  
  Low  

oTher DATA:

604 

617 

511 

481 

429 

8,507 

7,233 

6,554 

6,564 

  7,174 

$  70.75 
$  46.84 

$  58.63 
$  21.01 

$  23.91 
$  11.43 

$  11.77 
8.05 
$ 

$  12.49  
$  5.79 

Capital Expenditures and Deferred Turnaround 
  and Catalyst Costs  

$  3,756 

$  2,574 

$  1,596 

$  1,112 

$ 

780 

Number of Employees, End of Year  

  21,855 

  21,923 

  19,879 

  19,741 

  19,878 

operATiNg STATiSTicS:

Throughput Volumes (mbbls per day)  

2,960 

2,488 

2,162 

1,835 

  1,595 

Throughput Margin per Barrel 

$  12.29 

$  11.14 

$ 

7.44 

$ 

5.13 

$  4.02 

Operating Costs per Barrel: 

  Refining Operating Expenses 
  Depreciation and Amortization 

$ 

3.50 
0.95 

$ 

3.16 
0.80 

$ 

2.65 
0.66 

$ 

2.43 
0.62 

$  2.26  
0.66 

  Total Operating Costs per Barrel 

$ 

4.45 

$ 

3.96 

$ 

3.31 

$ 

3.05 

$  2.92 

(a) 

 Includes the operations related to the Premcor Acquisition beginning September 1, 2005.

(b) 

 Includes the operations related to the Aruba Acquisition beginning March 5, 2004.

(c) 

 Includes the operations of the St. Charles Refinery beginning July 1, 2003.

VLO AR pages 14-28.indd   25

3/19/07   5:17:25 PM

Va l e r o   e n e r g y   C o r p o r a t i o n

23     

 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
Our Board of Directo rs

Left to Right
Senator Don Nickles retired in 2005 
as U.S. Senator from Oklahoma 
after 24 years. As a U.S. Senator, 
he served as Assistant Republican 
Leader, Chairman of the Republican 
Senatorial Committee, Chairman of 
the Republican Policy Committee and 
Chairman of the Budget Committee. 
He also served on the Finance 
and Energy and Natural Resources 
committees. Upon his retirement, he 
formed and became Chairman and 
Chief Executive Officer of The Nickles 
Group. He also serves on the Board 
of Chesapeake Energy Corporation 
and Fortress America Acquisition 
Corporation. 

bob profusek is a partner in the Jones 
Day law firm and heads their Mergers 
and Acquisitions department. Mr. 
Profusek also serves as a director 
of CTS Corporation. Previously, he 
served as Executive Vice President of 
Omnicom Group Inc. and as a director 
of the managing general partner of 
Valero L.P.

Dr. Susan kaufman purcell is the 
Director of the Center for Hemispheric 
Policy at the University of Miami. 
This center examines the relationship 
between the U.S. and Latin 
America with respect to economic 
development, trade, healthcare and 
politics. Previously, Dr. Purcell served 
as Vice President of the Americas 
Society and Vice President of the 
Council of the Americas.

Jerry choate is retired from Allstate 
Corporation, where he served as 
Chairman of the Board and Chief 
Executive Officer from 1995 through 
the end of 1998. Currently, Mr. Choate 
serves as a director of Amgen, Inc., 
H&R Block and Van Kampen Mutual 
Funds. 

bill klesse is CEO and Chairman of the 
Board of Valero Energy Corporation. 
He was elected Chairman of the Board 
in January 2007, and was named CEO 
and Vice Chairman of the Board at the 
end of 2005. Previously, Mr. Klesse 
served as Valero’s Executive Vice 
President and Chief Operating Officer, 
and held other leadership positions 
with Valero, Ultramar Diamond 
Shamrock and Diamond Shamrock 
Corporation since 1969.

Dr. ron calgaard serves as Chairman 
of the Ray Ellison Grandchildren 
Trust, and as a director of The Trust 
Company, N.A. Previously, he served 
as Chairman and Chief Executive 
Officer of Austin, Calvert & Flavin, 
Inc. in San Antonio. Prior to that, he 
was President of Trinity University 
in San Antonio from 1979 until his 
retirement in 1999, at which time he 
was appointed President Emeritus of 
the University.

bill bradford is the retired Chairman 
of the Board of Halliburton Company.  
Prior to the Halliburton-Dresser 
merger, he was Chairman of the 
Board and Chief Executive Officer of 

Dresser Industries, Inc., and he held 
various positions in production and 
management during his tenure there.  

bob marbut is Chairman of the Board 
and Chief Executive Officer of Argyle 
Communications, Inc. and Chairman 
of SecTecGLOBAL, Inc. He also serves 
as Executive Chairman of Electronics 
Line 3000 Ltd., and as Chairman and 
Co-Chief Executive Officer of Argyle 
Security Acquisition Corporation. 
He is a director of Tupperware 
Brands Corporation and Hearst-
Argyle Television, Inc. Previously, Mr. 
Marbut led Hearst-Argyle Television, 
Inc.; Argyle Television, Inc.; Argyle 
Television Holding, Inc.; and Harte-
Hanks Communications, Inc.

irl engelhardt is Chairman of the 
Board of Peabody Energy Corporation. 
He served as Peabody’s Chairman and 
Chief Executive Officer from 1993 
through 2005 when he retired as Chief 
Executive Officer.  Prior to that, he 
served as Chief Executive Officer of 
a predecessor of the company. Mr. 
Engelhardt is also a director of The 
Williams Companies, Inc., and is 
Chairman of The Federal Reserve Bank 
of St. Louis.

ruben escobedo, a Certified Public 
Accountant, has had his own certified 
public accounting firm, Ruben 
Escobedo & Company, CPAs, in San 
Antonio since its formation in 1977. 
He also serves as a director of Cullen/
Frost Bankers, Inc.

24     

Va l e r o   e n e r g y   C o r p o r a t i o n

VLO AR pages 14-28.indd   26

3/19/07   5:17:35 PM

Sh a reho lde r	Information

Media Inquiries
Media	inquiries,	please	contact:
Corporate	Communications
P.O.	Box	696000
San	Antonio,	TX	78269-6000
(800)	531-7911	or	(210)	345-2000
(210)	345-2327	(fax)
corporatecommunications@valero.com

Annual Meeting
Valero’s	annual	meeting	of	
stockholders	will	be	held	at	10	a.m.,	
Thursday,	April	26,	2007,	at	Valero’s	
corporate	headquarters	located	at	One	
Valero	Way	(near	the	southwest	corner	
of	the	intersection	of	I.H.	10	and	Loop	
1604	West)	in	San	Antonio,	Texas.		

Transfer Agent and Registrar 
Computershare	Investor	Services	has	
been	appointed	transfer	agent,	registrar	
and	dividend	disbursing	agent	for	
Valero’s	common	stock.		Inquiries	
with	respect	to	stock	accounts	and	
dividends	and	all	requests	to	transfer	
certificates	should	be	addressed	to:

Computershare	Investor	Services	LLC
250	Royall	Street,	Mail	Stop	1A
Canton,	MA	02021
(888)	470-2938
(312)	360-5261
www.computershare.com/contactus

Dividend Withholding
under	federal	income	tax	law,	you	
are	subject	to	certain	penalties,	as	
well	as	withholding	with	respect	
to	your	dividend	payments,	if	you	
have	not	provided	Valero	with	your	
correct	social	security	number	or	
other	taxpayer	identification	number.		
For	this	reason,	any	security	holder	
who	has	not	provided	a	taxpayer	
identification	number	should	obtain	a	
Form	W-9	(Payer’s	Request	for	Taxpayer	
Identification	number).	To	request	
a	Form	W-9,	please	contact	Valero’s	
transfer	agent	and	registrar	at	the	
address	shown	above.		

Principal Officers
Bill Klesse,	CEO	&	Chairman	of	the
			Board
Greg King,	President
Mike Ciskowski,	Executive	Vice	
			President	&	Chief	Financial	Officer
Gene Edwards,	Executive	Vice		
			President	–	Corporate	Development	
			&	Strategic	Planning
Joe Gorder,	Executive	Vice	President	
			–	Marketing	&	Supply
Rich Marcogliese,	Executive	Vice		
			President	–	Operations
Gary Arthur Jr.,	Senior	Vice	President	
			–	Retail	Marketing	
Kim Bowers,	Senior	Vice	President	&	
			General	Counsel
Mary Rose Brown,	Senior	Vice	
			President	–	Corporate	
			Communications
Jay Browning,	Senior	Vice	President	–	
			Corporate	Law	&	Secretary
Mike Crownover,	Vice	President	–	
			Human	Resources
Clay Killinger,	Vice	President	&	
			Controller
Norm Renfro,	Vice	President	–	
			Health,	Safety	&	Environmental
Hal Zesch,	Vice	President	&	Chief	
			Information	Officer
Donna Titzman,	Treasurer	
Steve Gilbert,	Assistant	Secretary	&	
			Disclosure	&	Compliance	Officer

Valero Corporate Headquarters
One	Valero	Way		
San	Antonio,	TX	78249-1616
(210)	345-2000

Web Site
www.valero.com

Valero Energy Corporation 
Common Stock
Valero’s	common	stock	is	listed	
for	trading	on	the	new	york	Stock	
Exchange	under	the	ticker	symbol	
“VLO.”

Investor Inquiries
Investor	inquiries,	please	contact:	
Investor	Relations
P.O.	Box	696000
San	Antonio,	TX	78269-6000
(800)	531-7911	or	(210)	345-2000
(210)	345-2103	(fax)
investorrelations@valero.com

Forward-Looking Statements
Much	of	the	information	provided	
in	this	report	includes	or	is	based	
upon	estimates,	predictions,	
projections	and	other	“forward-
looking	statements”	(as	defined	
in	Section	27A	of	the	Securities	
Act	of	1933	and	Section	21E	of	
the	Securities	Exchange	Act	of	
1934)	that	involve	various	risks	
and	uncertainties.		While	these	
forward-looking	statements,	and	
any	assumptions	upon	which	
they	are	based,	are	made	in	good	
faith	and	reflect	Valero’s	current	
judgment	regarding	the	direction	
of	its	business,	actual	results	will	
almost	always	vary,	sometimes	
materially,	from	any	estimates,	
predictions,	projections,	
assumptions,	or	other	future	
performance	suggested	herein.		
Certain	risks	and	uncertainties	
that	may	affect	Valero	are	detailed	
from	time	to	time	in	its	SEC	
reports,	including	Valero’s	most	
recent	Annual	Report	on	Form	
10-K.		The	financial	and	other	
information	provided	in	this	
summary	annual	report	should	be	
read	in	conjunction	with	Valero	
Energy	Corporation’s	complete	
Consolidated	Financial	Statements	
(including	the	notes)	and	
Management’s	Discussion	and	
Analysis	of	Financial	Condition	
and	Results	of	Operations.	This	
and	other	information	about	
Valero	is	contained	in	Valero’s	
notice	of	the	2007	Annual	
Meeting	of	Stockholders	Proxy	
Statement	and	Form	10-K	for	
the	year	ended	December	31,	
2006.		This	document	is	provided	
to	all	stockholders	of	record	as	
of	March	1,	2007.		In	addition,	
persons	may	request,	without	
charge,	a	Form	10-K	by	writing	or	
calling	Valero’s	Investor	Relations	
Department.		Valero’s	2006	
Annual	Report	on	Form	10-K	and	
the	Proxy	Statement	also	may	
be	accessed	via	our	Web	site	at:	
www.valero.com.

						Printed	in	the	u.S.A.

Va l e r o   e n e r g y   C o r p o r a t i o n

25     

	
	
						
Valero	Energy	Corporation
P.0. Box 696000 • San Antonio, Texas 78269-6000 • www.valero.com